Conducting single-molecule magnet materials

Dalton Transactions : an International Journal of Inorganic Chemistry
Goulven CosquerMasahiro Yamashita

Abstract

Multifunctional molecular materials exhibiting electrical conductivity and single-molecule magnet (SMM) behaviour are particularly attractive for electronic devices and related applications owing to the interaction between electronic conduction and magnetization of unimolecular units. The preparation of such materials remains a challenge that has been pursued by a bi-component approach of combination of SMM cationic (or anionic) units with conducting networks made of partially oxidized (or reduced) donor (or acceptor) molecules. The present status of the research concerning the preparation of molecular materials exhibiting SMM behaviour and electrical conductivity is reviewed, describing the few molecular compounds where both SMM properties and electrical conductivity have been observed. The evolution of this research field through the years is discussed. The first reported compounds are semiconductors in spite being able to present relatively high electrical conductivity, and the SMM behaviour is observed at low temperatures where the electrical conductivity of the materials is similar to that of an insulator. During the recent years, a breakthrough has been achieved with the coexistence of high electrical conductivity and SMM...Continue Reading

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Citations

May 11, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Hongshan KeSanping Chen
May 23, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sarah DaleMartin T Lemaire
May 31, 2019·Chemistry : a European Journal·Keiko Komori-OrisakuShin-Ichi Ohkoshi
Oct 17, 2019·Chemistry : a European Journal·Olaf Stefańczyk, Shin-Ichi Ohkoshi
Nov 30, 2019·Angewandte Chemie·Yongbing ShenMasahiro Yamashita
Sep 10, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Soumava BiswasMasahiro Yamashita
Mar 4, 2021·Journal of the American Chemical Society·Yongbing ShenMasahiro Yamashita
Jun 23, 2021·Journal of the American Chemical Society·Yongbing ShenMasahiro Yamashita
Nov 4, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Agnieszka PuzanSzymon Chorazy

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BETA
X-ray

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