Constructing functionalized plasmonic gold/titanium dioxide nanosheets with small gold nanoparticles for efficient photocatalytic hydrogen evolution

Journal of Colloid and Interface Science
Lei ChengQuanjun Xiang

Abstract

Small plasmonic Au nanoparticles (NPs)-decorated with TiO2 nanosheets were fabricated to improve the photocatalytic performance. The Au/TiO2 nanosheets with Au NPs of different sizes ranging from ∼3 nm to 28 nm were prepared by using hydrothermally obtained TiO2 nanosheets as substrate via urea and light reduction method. During synthesis, the obtained Au NPs through urea reduction treatment in different calcination temperatures possessed smaller size (∼3-13 nm) than those of the light reduction method (∼28 nm). The introduced Au NPs were tightly loaded on the surface of TiO2 nanosheets through in situ growth reduction process of chloroauric acid. The emergence of smaller Au NPs promoted the photocatalytic performance over Au/TiO2 nanosheets. The as-prepared Au/TiO2 nanosheets with small Au NP sizes of ∼3-5 nm showed the highest photocatalytic rate of hydrogen production (∼230 µmol·h-1) under xenon lamp illumination, exceeding more than twice that of Au/TiO2 nanosheets with loading of larger Au NPs (∼28 nm). The favorable constituents and combination of Au/TiO2 nanosheets provided large surface adsorptive sites for reactant adsorption, introduced plasmonic effects and formed Schottky barrier junction via surface plasmon resonan...Continue Reading

Citations

Jan 31, 2020·Chemical Communications : Chem Comm·Fang LiQuanjun Xiang
Feb 25, 2020·Nanoscale Horizons : the Home for Rapid Reports of Exceptional Significance in Nanoscience and Nanotechnolgy·Yang LiQuanjun Xiang
Dec 29, 2020·Journal of Colloid and Interface Science·Yuwei LiaoYaorong Su

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