Construction of a porous homochiral coordination polymer with two types of Cu(n)I(n) alternating units linked by quinine: a solvothermal and a mechanochemical approach

Chemistry : a European Journal
Daniel ProchowiczJanusz Lewiński

Abstract

The polymer network: The reaction of quinine (QN) with CuI under solvothermal, as well as liquid-assisted grinding, conditions afforded a unique 1D homochiral coordination polymer {[Cu(4)(μ(3)-I)(4)(QN)(2)][Cu(3)(μ(3)-I)(2)(μ(2)-I)(QN)(2)](2)}(n), containing both triangular Cu(3)I(3) and cubane Cu(4)I(4) clusters as connecting nodes (see scheme). Van der Waals interactions between the adjacent 1D polymer chains lead to an extended quasi-honeycomb homochiral pillared 3D network with solvent-free 1D channels.

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Citations

Feb 11, 2015·Chemical Communications : Chem Comm·D ProchowiczJ Lewiński
Oct 24, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Thomas E ShawTitel Jurca
Jun 5, 2020·Chemical Communications : Chem Comm·Muxin YuMaochun Hong
Dec 25, 2015·Soft Matter·Kinga RoszakKarol Kacprzak
Feb 19, 2021·Chemical Society Reviews·Javier TroyanoSalomé Delgado
Nov 9, 2019·Accounts of Chemical Research·Daniel ProchowiczJanusz Lewiński
Oct 9, 2018·Inorganic Chemistry·Daniel ProchowiczJanusz Lewiński
Oct 23, 2018·Inorganic Chemistry·Adrien SchlachterPierre D Harvey
Apr 20, 2018·Inorganic Chemistry·Michał K LeszczyńskiJanusz Lewiński

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