Construction of Cluster Organic Frameworks with bnn Hexagonal BN Topologies

Chemistry : a European Journal
Wei-Hui FangGuo-Yu Yang

Abstract

Two sandwiched cluster organic frameworks, Eu6 (OH)2 Cu9 I6 L12 (ox)3 ⋅H2 O⋅ClO4 (FJ-23, HL=4-pyridin- 4-yl-benzonic acid, ox=oxalate) and Eu6 Cu7 I7 L12 (OAc)6 (H2 O)2 ⋅2 H2 O (FJ-24, OAc=acetate) with bnn hexagonal BN topologies have been successfully made; these frameworks were assembled by nanosized graphene-like lanthanide wheel clusters and nanoscale trigonal prism metalloligands. The cooperation of small equatorial ligands and axially trigonal prism metalloligands plays a key role in the construction of such 5-connected nets. Furthermore, the thermal stabilities and chiral characteristics were also studied.

References

Jul 18, 2001·Journal of the American Chemical Society·D L LongM Schröder
Jan 22, 2002·Inorganic Chemistry·Ruiyao WangRichard J Staples
May 15, 2003·Chemical Communications : Chem Comm·L Gunnar WestinAndrea Caneschi
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Citations

Dec 2, 2017·Chemistry : a European Journal·Peng JingPeng Cheng
Jun 5, 2018·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Shouquan Huo
Feb 6, 2019·Acta Crystallographica. Section C, Structural Chemistry·Tao QinSu Jing
Aug 2, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Ya-Nan FengShao-Wu Du
Oct 10, 2018·Accounts of Chemical Research·Wei-Hui Fang, Guo-Yu Yang

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