Controlling Configurational Isomerism in Three-Component Colloidal Hybrid Nanoparticles

Accounts of Chemical Research
James M Hodges, Raymond E Schaak

Abstract

Colloidal hybrid nanoparticles are solution-dispersible constructs that join together multiple distinct nanoscale materials through direct solid-solid interfaces. Given their multifunctionality and synergistic properties that emerge from interfacial coupling, hybrid nanoparticles are of interest for applications in biomedical imaging, solar energy conversion, heterogeneous catalysis, nanophotonics, and beyond. High-order hybrid nanoparticles, which incorporate three or more nanocrystal domains, offer greater tunability and functional diversity relative to one or two-component nanoparticles. The multiple heterojunctions within these structures can facilitate complex electromagnetic coupling as well as cooperative surface processes. Additionally, these materials can be used as model systems for studying fundamental structure-property relationships at the nanoscale that arise from particle coupling and interfacial exchanges. Limiting these advances is the inability to synthesize hybrid nanoparticles with precise morphologies and geometries. High-order hybrid nanoparticles can adopt more than one configuration, and each unique arrangement will have different heterointerfaces and, accordingly, different functions. Seeded-growth meth...Continue Reading

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Citations

May 20, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexander N Chen, Sara E Skrabalak
Jan 25, 2020·Science·Benjamin C SteimleRaymond E Schaak
Mar 2, 2019·Science·Peng-Cheng ChenChad A Mirkin
Jan 15, 2021·Accounts of Chemical Research·Jinxing ChenYadong Yin
Jul 2, 2021·Advanced Science·Stefanos MourdikoudisAlec P LaGrow
Sep 16, 2020·Journal of the American Chemical Society·Mingzhu LiuMarcus Weck
Apr 11, 2018·Journal of the American Chemical Society·Eric A MarroRebekka S Klausen
Oct 8, 2020·Accounts of Chemical Research·Raymond E SchaakJulie L Fenton

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