Controlling the cleavage of the inter- and intra-molecular linkages in lignocellulosic biomass for further biorefining: A review

Bioresource Technology
Zhicheng JiangChangwei Hu

Abstract

The abundant intermolecular linkages among cellulose, hemicellulose and lignin significantly limit the utilization of the most promising renewable biomass. Process control with solvents, catalysts and temperature is of significant importance providing ways to break the above linkages, and benefiting to the further conversion of the main biomass components to small molecular products. This article discusses the effect of catalyst under hydrothermal and organosolv treatment emphasizing the cleavage of the intermolecular linkage. Acidic catalysts show good performance on cleaving the linkages between carbohydrates and lignin. Basic catalysts promoted the dissolution of lignin component. Hydrogenolysis assisted conversion of lignin can efficiently break the intermolecular linkages to yield lignin-derived bio-oil, especially in co-solvent reaction system. Besides, the effects of single solvent and co-solvent systems, as well as the cleavage of the intramolecular linkages to yield target chemicals are also included. Several further study strategies are proposed.

Citations

Oct 24, 2020·The Science of the Total Environment·Amaia MoralesPatricia Gullón
Mar 30, 2020·Bioresource Technology·Petter Paulsen ThoresenPaul Christakopoulos

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.