Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes

Chemical Communications : Chem Comm
Priyabrata GhanaJun Okuda

Abstract

By using a triaryl-Tren ligated titanium dinitrogen complex, K2[{(Xy-N3N)Ti}2(μ2-N2)] (3), prepared by two-electron reduction of [TiCl(Xy-N3N)] (1-Cl) under N2 atmosphere, catalytic fixation of molecular nitrogen to form tris(trimethylsilyl)amine was achieved under ambient conditions with a turnover number (TON) of up to 16.5 per titanium atom.

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Citations

Nov 14, 2019·Chemical Communications : Chem Comm·Ryosuke KawakamiYoshiaki Nishibayashi
Oct 20, 2020·European Journal of Inorganic Chemistry·Mary C EatonLeslie J Murray
Sep 12, 2020·Chemistry : a European Journal·Fabio MaseroVictor Mougel
Apr 24, 2021·Angewandte Chemie·Priyabrata GhanaJun Okuda
Dec 2, 2020·Inorganic Chemistry·Anders ReinholdtDaniel J Mindiola
May 28, 2020·Chemical Reviews·Sangmin KimPaul J Chirik
Sep 9, 2021·Inorganic Chemistry·Dae Young BaeEunsung Lee
Oct 13, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Dae Young BaeEunsung Lee
Jan 12, 2022·Journal of the American Chemical Society·Guoqiang ZhangQian Liao

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Methods Mentioned

BETA
NMR
X-ray

Software Mentioned

CONDON

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