CO/O2 assisted oxidative carbon-carbon and carbon-heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins

Chemical Science
Ailong ShaoAiwen Lei

Abstract

Selective carbon-carbon and carbon-heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative oxosulfonation of olefins with DMSO has been developed. Preliminary mechanistic investigations indicated that CO/O2 assisted the bond cleavage and the leaving groups from the starting materials were trapped by O2 and underwent a hydroxylation process.

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Citations

Sep 27, 2019·Chemical Communications : Chem Comm·Zongchao LvAiwen Lei
May 28, 2020·Chemical Society Reviews·Jiang LouZhengkun Yu
Apr 23, 2021·Organic & Biomolecular Chemistry·Raju Jannapu ReddyJangam Jagadesh Kumar
Mar 21, 2020·Organic Letters·Asim Kumar GhoshAlakananda Hajra
Dec 25, 2019·The Journal of Organic Chemistry·Duo FuJiaxi Xu

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