Cooperative Conical Intersection Dynamics of Two Pyrazine Molecules in an Optical Cavity

The Journal of Physical Chemistry Letters
Bing Gu, Shaul Mukamel

Abstract

Hybrid light-matter states in optical cavities, known as polaritons, offer a novel means of manipulating and controlling photochemical processes. We investigate the cooperative cavity photochemistry of two pyrazine molecules undergoing conical intersection dynamics and interacting with a single cavity photon mode by exact quantum dynamics. When the cavity mode is coupled to the electronic transition between the ground and excited states, we find an enhanced polaritonic splitting and collective dark states. These features dominate the cooperative polariton dynamics and can be observed in the transient absorption spectrum.

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Citations

Dec 12, 2020·Angewandte Chemie·Abhijit SauThomas W Ebbesen
Feb 17, 2021·The Journal of Chemical Physics·Tamás SzidarovszkyÁgnes Vibók
Feb 23, 2021·The Journal of Physical Chemistry Letters·Bing Gu, Shaul Mukamel
Jul 11, 2021·Science·Francisco J Garcia-VidalThomas W Ebbesen
Aug 16, 2021·The Journal of Chemical Physics·Aleksandr G Avramenko, Aaron S Rury
Sep 3, 2020·The Journal of Physical Chemistry Letters·Bing Gu, Shaul Mukamel
Jul 18, 2020·The Journal of Physical Chemistry Letters·Gregory D ScholesBryan Kudisch
Sep 28, 2021·The Journal of Physical Chemistry Letters·Pei-Yun Yang, Jianshu Cao
Oct 6, 2021·Journal of the American Chemical Society·Kalaivanan NagarajanThomas W Ebbesen
Jan 28, 2022·The Journal of Physical Chemistry Letters·Csaba FábriÁgnes Vibók

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