Coordination chemistry of N-heterocyclic nitrenium-based ligands

Chemistry : a European Journal
Yuri TulchinskyMark Gandelman

Abstract

Comprehensive studies on the coordination properties of tridentate nitrenium-based ligands are presented. N-heterocyclic nitrenium ions demonstrate general and versatile binding abilities to various transition metals, as exemplified by the synthesis and characterization of Rh(I) , Rh(III) , Mo(0) , Ru(0) , Ru(II) , Pd(II) , Pt(II) , Pt(IV) , and Ag(I) complexes based on these unusual ligands. Formation of nitrenium-metal bonds is unambiguously confirmed both in solution by selective (15) N-labeling experiments and in the solid state by X-ray crystallography. The generality of N-heterocyclic nitrenium as a ligand is also validated by a systematic DFT study of its affinity towards all second-row transition and post-transition metals (Y-Cd) in terms of the corresponding bond-dissociation energies.

References

Oct 30, 2004·Chemical Communications : Chem Comm·Dietrich GudatMartin Nieger
Feb 12, 2011·Chemical Communications : Chem Comm·Gregory S DayChristine M Thomas
Jun 24, 2011·Nature Chemistry·Yuri TulchinskyMark Gandelman
May 5, 2012·Accounts of Chemical Research·Sharon R Neufeldt, Melanie S Sanford
Jan 2, 2014·Journal of the American Chemical Society·Florian HeimsKallol Ray

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Citations

Aug 17, 2016·Accounts of Chemical Research·Manuel Alcarazo
Feb 28, 2017·Journal of the American Chemical Society·Alla PogoreltsevMark Gandelman
Jun 3, 2017·Journal of the American Chemical Society·Tyler E StevensKaren I Goldberg
Mar 13, 2018·Chemical Communications : Chem Comm·Jiliang ZhouDouglas W Stephan
May 29, 2018·Angewandte Chemie·Alexander E WakedDouglas W Stephan
Jan 18, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Latchupatula RadhakrishnaMaravanji S Balakrishna
Nov 3, 2020·Chemistry : a European Journal·Diya ZhuDouglas W Stephan
Jan 7, 2021·Angewandte Chemie·Idan AvigdoriMark Gandelman
Aug 24, 2021·Inorganic Chemistry·Allan G BlackmanPaul V Bernhardt
Mar 21, 2020·Inorganic Chemistry·Nagarjuna Kumar SrungavrukshamChing-Wen Chiu

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