Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

Dalton Transactions : an International Journal of Inorganic Chemistry
Michael A LandJason A C Clyburne

Abstract

In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N'-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.

References

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Citations

Aug 15, 2019·Inorganic Chemistry·Sanjib PandaGoutam Kumar Lahiri

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Methods Mentioned

BETA
X-ray
NMR
column chromatography

Software Mentioned

TwinRotMax
OPUS
SHELXL
SHELXS
Mercury CSD
Platon
SHELXT
Bruker SAINT

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