Copper-Catalyzed Borylcupration of Allenylsilanes

Angewandte Chemie
Weiming YuanShengming Ma

Abstract

A highly regio- and stereoselective copper-catalyzed borylcupration of 1,2-allenylsilanes affords an unexpected regioreversed allylic boronate bearing an extra C-Si bond at the 3-position, with a thermodynamically disfavored Z geometry. Such stereodefined allylic boronates containing an extra alkenyl silane moiety are very useful organodimetallic reagents for organic synthesis.

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Citations

Jul 20, 2016·Chemical Reviews·Emily C NeeveTodd B Marder
Jul 21, 2016·Journal of the American Chemical Society·Wanxiang Zhao, John Montgomery
Oct 31, 2017·Chemistry : a European Journal·Carlos Jarava-BarreraMariola Tortosa
Nov 6, 2020·Organic & Biomolecular Chemistry·Bing-Xue ShenQing-An Chen
Oct 4, 2018·Journal of the American Chemical Society·Can ZhuJan-E Bäckvall

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