Copper-mediated cross-coupling of 1,1-dibromo-1-alkenes with dialkyl phosphites: a convenient synthesis of 1-alkenylphosphonates

Chemical Communications : Chem Comm
Gwilherm EvanoFrançois Couty

Abstract

An efficient and stereoselective procedure for the preparation of E-1-alkenylphosphonates by copper-mediated cross-coupling between 1,1-dibromo-1-alkenes and dialkyl phosphites is reported. The reaction allows for formal substitution of both bromine atoms, respectively, by an hydrogen and a dialkoxyphosphoryl.

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Citations

Nov 17, 2011·Chemical Reviews·Giorgio Chelucci
Jan 27, 2011·Chemical Communications : Chem Comm·Elise BernoudAnnie-Claude Gaumont
Mar 26, 2014·The Journal of Organic Chemistry·Yulei WangYufen Zhao
Aug 27, 2014·Chemical Communications : Chem Comm·Alexandre Pradal, Gwilherm Evano
Apr 1, 2015·Organic Letters·Liping ZhuRui Wang
Aug 2, 2014·The Journal of Organic Chemistry·Yile WuYufen Zhao
Oct 9, 2012·Chemistry : a European Journal·Ekaterina V VinogradovaRoger Guilard
Jun 30, 2015·Organic & Biomolecular Chemistry·Arun Jyoti Borah, Guobing Yan
Mar 27, 2015·Organic & Biomolecular Chemistry·Jian-Fei XueOlayinka Taiwo Asekun
Nov 4, 2020·Chemical Communications : Chem Comm·Laura CastoldiBerit Olofsson
Nov 10, 2018·The Journal of Organic Chemistry·Pierre ThilmanyGwilherm Evano
Apr 13, 2018·Inorganic Chemistry·Werner Oberhauser, Gabriele Manca
Nov 15, 2017·Organic Letters·Antoine NiteletGwilherm Evano
Nov 25, 2021·The Journal of Organic Chemistry·Biplab Keshari PandiaChidambaram Gunanathan

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