Copper-mediated stereospecific C-H oxidative sulfenylation of terminal alkenes with disulfides

Chemical Communications : Chem Comm
Hai-Yong TuXing-Guo Zhang

Abstract

A copper and iodine-mediated C-H oxidative sulfenylation of olefins with diaryl disulfides has been developed for the stereospecific synthesis of vinyl thioether. With the combination of Cu(OTf)2 and I2, a variety of terminal alkenes underwent oxidative coupling reaction with various diaryl disulfides successfully to afford the corresponding E-vinyl sulfides in moderate to good yields.

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Citations

Jan 12, 2019·Chemical Communications : Chem Comm·Wei Feng, Xing-Guo Zhang
May 30, 2020·Chemistry : a European Journal·Honghua ZhangZhen Wang
Jan 27, 2021·Chemical Communications : Chem Comm·Ying-Qiong GuoXing-Guo Zhang
Jun 17, 2021·Organic & Biomolecular Chemistry·Rui WangHuaiqing Zhao
Jul 17, 2019·The Journal of Organic Chemistry·Xiao LiangYuanjiang Pan

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