Copper(I)-catalyzed heteroannulation of [60]fullerene with ketoxime acetates: preparation of novel 1-fulleropyrrolines

Chemical Communications : Chem Comm
Sheng-Peng JiangGuan-Wu Wang

Abstract

A cuprous bromide-catalyzed heteroannulation reaction of [60]fullerene with ketoxime acetates has been exploited to prepare novel 1-fulleropyrrolines through the cleavage of N-O and C-H bonds and formation of C-C and C-N bonds under thermal conditions. A plausible mechanism for the formation of 1-fulleropyrrolines is proposed on the basis of the experimental results. The electrochemistry of the obtained products has also been investigated.

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Citations

Jan 16, 2016·The Journal of Organic Chemistry·Hai-Tao YangChun-Bao Miao
Mar 28, 2017·Organic & Biomolecular Chemistry·Jun-Jie WangGuan-Wu Wang
Feb 25, 2020·Organic & Biomolecular Chemistry·Atul UpareSurendar Reddy Bathula
Sep 28, 2017·Organic & Biomolecular Chemistry·Michio YamadaYutaka Maeda
Mar 9, 2021·Chemical Communications : Chem Comm·Jindian DuanKai Guo
Jun 26, 2021·Chemical Communications : Chem Comm·Wen-Qiang LuGuan-Wu Wang
Sep 14, 2017·The Journal of Organic Chemistry·Sheng-Peng JiangGuan-Wu Wang
Jan 30, 2018·The Journal of Organic Chemistry·Sheng-Li Wu, Xiang Gao

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