Copper(II)/phenanthroline-mediated CD-enhancement and chiral memory effect on a meta-ethynylpyridine oligomer

Chemical Communications : Chem Comm
Shunsuke TakashimaMasahiko Inouye

Abstract

meta-Ethynylpyridine 18-mer associates with octyl β-D-glucopyranoside to show an induced circular dichroism (CD) band at around 337 nm in CH(2)Cl(2). The addition of copper(II) triflate and o-phenanthroline enhanced the CD band. Even when an equimolar amount of β-L-glucopyranoside was added to make the system racemic, the CD was memorized and remained for several weeks.

References

Dec 13, 2001·Chemical Reviews·D J HillJ S Moore
Dec 13, 2001·Chemical Reviews·T Nakano, Y Okamoto
Sep 18, 2003·Journal of the American Chemical Society·Susanne Striegler, Michael Dittel
Jan 22, 2004·Journal of the American Chemical Society·Masayoshi IshikawaEiji Yashima
Feb 20, 2004·Journal of the American Chemical Society·Masahiko InouyeHajime Abe
Apr 1, 2004·Proceedings of the National Academy of Sciences of the United States of America·Michael ReggelinMichael Holbach
Sep 30, 2004·Journal of the American Chemical Society·Jun-Li HouZhan-Ting Li
Apr 7, 2005·Journal of the American Chemical Society·Toyoharu MiyagawaEiji Yashima
Apr 12, 2005·Inorganic Chemistry·Susanne Striegler, Michael Dittel
Nov 17, 2005·Journal of the American Chemical Society·Hajime AbeMasahiko Inouye
Jul 19, 2006·Chemistry : a European Journal·Minoru WakiMasahiko Inouye
Apr 7, 2007·Organic Letters·Chuang LiRen-Xiao Wang
Apr 19, 2007·Chemistry, an Asian Journal·Zhan-Ting LiHui-Ping Yi
Mar 26, 2008·Accounts of Chemical Research·Zhan-Ting LiChuang Li
Aug 15, 2008·Journal of the American Chemical Society·Takehiro KawauchiEiji Yashima
Aug 30, 2008·Journal of the American Chemical Society·Naoki OusakaReiko Kuroda
Sep 16, 2008·Journal of the American Chemical Society·Wei CaiZhan-Ting Li
Nov 26, 2008·Chemical Communications : Chem Comm·Susanne Striegler, Moses G Gichinga
Apr 11, 2009·Chemical Communications : Chem Comm·Hajime AbeMasahiko Inouye
Nov 13, 2009·Chemical Reviews·Eiji YashimaKanji Nagai
Feb 20, 2010·Inorganic Chemistry·Susanne StrieglerAnna-Gay D Nelson
May 8, 2010·Chemical Society Reviews·Hemraj JuwarkerKyu-Sung Jeong
Aug 24, 2010·Chemical Society Reviews·Hemraj Juwarker, Kyu-Sung Jeong
Nov 10, 2010·Chemical Communications : Chem Comm·Gaku Fukuhara, Yoshihisa Inoue
Dec 22, 2010·Journal of the American Chemical Society·Gaku Fukuhara, Yoshihisa Inoue

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Citations

Sep 11, 2014·Chemical Society Reviews·Uwe H F BunzMichael Porz
Apr 2, 2019·Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan·Hajime Abe
May 11, 2019·Angewandte Chemie·Alan VanderkooyMáté Erdélyi
Jan 23, 2021·The Journal of Physical Chemistry Letters·Li YangChuanliang Feng
Sep 18, 2012·Organic Letters·Jae-Min SukKyu-Sung Jeong
Mar 29, 2018·Accounts of Chemical Research·Yann Ferrand, Ivan Huc
Jul 21, 2015·Chemical Reviews·Minghua LiuTianyu Wang

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