Copper/palladium synergistic catalysis for the syn- and anti-selective carboboration of alkenes

Angewandte Chemie
Kaitlyn M LoganM Kevin Brown

Abstract

A method for the diastereoselective carboboration of 1,2-disubstituted styrenes with aryl/vinyl bromides and (Bpin)2 is reported. High diastereoselectivities and yields are observed for the formation of either diastereomer of the product from a single alkene isomer. These reactions provide access to a diverse range of structures from simple starting materials.

References

Nov 16, 2002·Angewandte Chemie·Adam F Littke, Gregory C Fu
Jun 6, 2003·Journal of the American Chemical Society·Michinori SuginomeMasahiro Murakami
Apr 1, 2004·Angewandte Chemie·Shawn D WalkerStephen L Buchwald
Oct 8, 2004·Journal of the American Chemical Society·Jacqueline E Milne, Stephen L Buchwald
Dec 22, 2006·Chemistry : a European Journal·Vanesa LilloElena Fernández
Jan 31, 2007·Journal of the American Chemical Society·Juan Marco-MartínezDiego J Cardenas
May 16, 2009·Journal of the American Chemical Society·Chong Han, Stephen L Buchwald
Sep 18, 2010·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Michinori Suginome
Feb 1, 2011·Chemistry : a European Journal·Juan Marco-MartínezDiego J Cárdenas
Apr 21, 2012·Chemical Science·Anna E Allen, David W C Macmillan
Jan 29, 2013·Journal of the American Chemical Society·Koji KubotaHajime Ito
Feb 7, 2013·Organic Letters·Hiroto YoshidaKen Takaki
Dec 5, 2013·Chemistry : a European Journal·Laetitia Chausset-BoissarieCathleen M Crudden
Apr 2, 2014·Journal of the American Chemical Society·Smitha C MatthewCathleen M Crudden
May 8, 2014·Angewandte Chemie·Yang Yang, Stephen L Buchwald
May 9, 2014·Journal of the American Chemical Society·Kazuhiko Semba, Yoshiaki Nakao
Aug 13, 2014·Chemistry : a European Journal·Kevin B SmithM Kevin Brown
Sep 17, 2014·Journal of the American Chemical Society·Ling LiMark R Biscoe
Oct 11, 2014·Journal of the American Chemical Society·Wei You, M Kevin Brown

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Citations

Dec 29, 2015·The Journal of Organic Chemistry·Kai Yang, Qiuling Song
Oct 16, 2015·Journal of the American Chemical Society·Tao JiaJian Liao
Nov 14, 2015·Journal of the American Chemical Society·Wei You, M Kevin Brown
Jun 28, 2016·Journal of the American Chemical Society·Stig D FriisStephen L Buchwald
Jul 20, 2016·Chemical Reviews·Emily C NeeveTodd B Marder
Aug 5, 2016·Organic Letters·Kazuhiko SembaYoshiaki Nakao
Sep 21, 2016·Organic Letters·Daiki NishikawaMasahiro Miura
Nov 5, 2016·Organic Letters·Kai Yang, Qiuling Song
Apr 19, 2017·Angewandte Chemie·Akira SaitoMasakatsu Shibasaki
Jun 2, 2017·Journal of the American Chemical Society·Jillian R SanzoneK A Woerpel
Dec 22, 2016·Angewandte Chemie·Kaitlyn M Logan, M Kevin Brown
Jul 13, 2017·Journal of the American Chemical Society·Stephen R Sardini, M Kevin Brown
Jul 25, 2017·Journal of the American Chemical Society·Joseph DerosaKeary M Engle
Sep 28, 2017·Chemistry, an Asian Journal·Tian-Jun GongYao Fu
Aug 30, 2017·Angewandte Chemie·Yuan HuangM Kevin Brown
Jun 14, 2018·Chemistry, an Asian Journal·Ji-Shu ZhangLi-Biao Han
Sep 18, 2015·Chemistry : a European Journal·Taisuke ItohMotomu Kanai
Aug 31, 2018·Angewandte Chemie·Andrew WhyteMark Lautens
Sep 27, 2018·Chemical Communications : Chem Comm·Kazuhiko SembaYoshiaki Nakao
Sep 13, 2018·Chemical Society Reviews·David HemmingPatrick G Steel
Oct 30, 2018·Angewandte Chemie·Di WangZhuangzhi Shi
Dec 7, 2018·Angewandte Chemie·Allison M BergmannM Kevin Brown
Feb 12, 2019·Angewandte Chemie·Wang WangGuoyin Yin
Apr 11, 2019·Chemistry : a European Journal·Yusuke UedaMasaya Sawamura
Jun 6, 2019·Organic & Biomolecular Chemistry·Yuan HuangM Kevin Brown
Sep 14, 2019·Chemistry : a European Journal·Natalia Cabrera-LoberaDiego J Cárdenas
Nov 26, 2019·Chemistry : a European Journal·Yue WuWanbin Zhang
May 20, 2017·Angewandte Chemie·Beatrice S L CollinsVarinder K Aggarwal
May 5, 2020·Beilstein Journal of Organic Chemistry·Balaram S TakaleBruce H Lipshutz
May 6, 2020·Topics in Current Chemistry·Sina Matavos-AramyanMohammad Hossein Jazebizadeh

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