Covalently attached organic monolayers on SiC and SixN4 surfaces: formation using UV light at room temperature

Langmuir : the ACS Journal of Surfaces and Colloids
Michel RossoHan Zuilhof

Abstract

We describe the formation of alkyl monolayers on silicon carbide (SiC) and silicon-rich silicon nitride (SixN4) surfaces, using UV irradiation in the presence of alkenes. Both the surface preparation and the monolayer attachment were carried out under ambient conditions. The stable coatings obtained in this way were studied by water contact angle measurements, infrared reflection absorption spectroscopy, X-ray reflectivity, and X-ray photoelectron spectroscopy. Besides unfunctionalized 1-alkenes, methyl undec-10-enoate, and 2,2,2-trifluoroethyl undec-10-enoate were also grafted onto both substrates. The resulting ester-terminated surfaces could then be further reacted after hydrolysis using amide chemistry to easily allow the attachment of amine-containing compounds.

References

Dec 2, 1998·Archives of Orthopaedic and Trauma Surgery·S SantavirtaY T Konttinen
Sep 13, 2000·Nucleic Acids Research·T StrotherL M Smith
Feb 17, 2001·Angewandte Chemie·Jillian M. Buriak
Aug 9, 2001·Journal of the American Chemical Society·M P Stewart, J M Buriak
May 9, 2002·Chemical Reviews·Jillian M Buriak
Nov 13, 2003·Journal of the American Chemical Society·Louis C P M de SmetErnst J R Sudhölter
Nov 13, 2003·Journal of Biomedical Materials Research. Part a·Stuart F CoganRobyn Edell
Dec 5, 2003·Journal of the American Chemical Society·Fernando A ReboredoGiulia Galli
Jul 15, 2004·Journal of the American Chemical Society·Ahmed ArafatHan Zuilhof
Sep 8, 2004·Langmuir : the ACS Journal of Surfaces and Colloids·Ketul C PopatTejal A Desai
Nov 19, 2004·Biomedical Microdevices·A J RosenbloomW J Choyke
Dec 15, 2004·Langmuir : the ACS Journal of Surfaces and Colloids·Raluca VoicuDanial D M Wayner
Feb 24, 2005·Journal of the American Chemical Society·Qiao-Yu SunErnst J R Sudhölter
May 13, 2005·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Naoto ShirahataTetsu Yonezawa
Apr 13, 2006·Nano Letters·Y T YangM L Roukes
May 13, 2006·Journal of Materials Science. Materials in Medicine·A de CarlosB León
Jul 21, 2006·The Journal of Physical Chemistry. B·Beth M NicholsRobert J Hamers
Sep 20, 2006·Langmuir : the ACS Journal of Surfaces and Colloids·Trevor K MischkiDanial D M Wayner
Feb 15, 2007·Nano Letters·Aurel YmetiJohannes S Kanger
Apr 26, 2007·Langmuir : the ACS Journal of Surfaces and Colloids·Ahmed ArafatHan Zuilhof
Jun 26, 2007·Langmuir : the ACS Journal of Surfaces and Colloids·Luc ScheresHan Zuilhof
Sep 1, 2007·Analytica Chimica Acta·D K AswalD Vuillaume
Jan 31, 2008·Chemical Reviews·Colette McDonaghBrian D MacCraith
Jan 31, 2008·Chemical Reviews·Karen M GoedersLawrence A Bottomley
Jan 31, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Aaron S AndersonBasil I Swanson
Mar 8, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Michel RossoHan Zuilhof
Jul 16, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Menglong YangHan Zuilhof

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Citations

Jan 16, 2013·Biomedical Microdevices·Alexandra OliverosStephen E Saddow
Jun 28, 2011·Analytical Chemistry·Nianjun YangChristoph E Nebel
Sep 23, 2011·ACS Applied Materials & Interfaces·Roland DietmuellerMartin Stutzmann
Jan 30, 2013·ACS Applied Materials & Interfaces·Sebastian J SchoellIan D Sharp
Mar 23, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Yan LiChengzhi Cai
May 6, 2010·Chemical Communications : Chem Comm·Guoting QinChengzhi Cai
Nov 3, 2010·Chemical Communications : Chem Comm·Joel A KellyJonathan G C Veinot
Sep 28, 2010·Chemical Communications : Chem Comm·Jurjen ter MaatHan Zuilhof
Jan 23, 2016·Langmuir : the ACS Journal of Surfaces and Colloids·Matthias SachsenhauserJose A Antonio Garrido
May 23, 2014·Angewandte Chemie·Sidharam P PujariHan Zuilhof
Dec 20, 2012·Chemical Communications : Chem Comm·Radostina K ManovaTeris A van Beek
May 7, 2016·ACS Applied Materials & Interfaces·Ye TaoChristian L Degen
Dec 13, 2016·ACS Applied Materials & Interfaces·Y M Nuwan D Y BandaraJason R Dwyer
Dec 16, 2016·ACS Applied Materials & Interfaces·Marine BrunetFrançois Ozanam
Sep 21, 2018·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Nabi AghdassiHelmut Zacharias
Jan 26, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Benjamin KlingebielNils Hartmann
Jun 22, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Tuha VongHan Zuilhof
Jul 9, 2009·Langmuir : the ACS Journal of Surfaces and Colloids·Jurjen ter MaatHan Zuilhof
Aug 15, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Yan LiHan Zuilhof
Jul 4, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Ryan FrankingRobert J Hamers
May 31, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Radostina K ManovaTeris A van Beek
May 16, 2014·Langmuir : the ACS Journal of Surfaces and Colloids·Nagendra S BhairamadgiHan Zuilhof
Nov 4, 2017·Langmuir : the ACS Journal of Surfaces and Colloids·Sergei AlekseevVladimir Lysenko
Feb 5, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Ai T NguyenHan Zuilhof
Aug 8, 2013·Langmuir : the ACS Journal of Surfaces and Colloids·Sidharam P PujariHan Zuilhof
Aug 9, 2013·Langmuir : the ACS Journal of Surfaces and Colloids·Sidharam P PujariHan Zuilhof
Jul 8, 2014·ACS Applied Materials & Interfaces·Julie C WhelanJason R Dwyer
Feb 12, 2011·ACS Applied Materials & Interfaces·Michel RossoHan Zuilhof
Feb 14, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Yan Li, Han Zuilhof
Nov 9, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Ai T NguyenCees J M van Rijn
Jul 28, 2019·ACS Applied Materials & Interfaces·Y M Nuwan D Y BandaraJason R Dwyer
Feb 25, 2015·Langmuir : the ACS Journal of Surfaces and Colloids·Jose Maria AlonsoHan Zuilhof
Feb 21, 2013·The Journal of Physical Chemistry Letters·Gary F Moore, Ian D Sharp

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