Cracking the framework of bulk CuCN with flexible bipyrazolyl-based ligands to assemble [CuCN]n-based coordination polymers

Dalton Transactions : an International Journal of Inorganic Chemistry
Ling-Ling LiJian-Ping Lang

Abstract

Solvothermal reactions of CuCN with a set of flexible bipyrazolyl-based ligands with different spacer lengths [(dmpz)(CH(2))(n)(dmpz)] (dmpz = 3,5-dimethyl-pyrazolyl; n = 1-6) gave rise to six [CuCN](n)-based coordination polymers [(CuCN)(3)L](n) (1: L = dmpzm; 2: L = dmpze), [(CuCN)(2)L](n) (3: L = dmpzpr; 4: L = dmpzb; 5: L = dmpzp; 6: L = dmpzh). Compounds 1-6were characterized by elemental analysis, IR, powder X-ray diffraction and single-crystal X-ray diffraction. 1 or 2 exhibits a 1D scolopendra-like chain assembled from a rare 1D zigzag [CuCN](n) chain with [CN-Cu-CN-Cu-L] (1: L = dmpzm; 2: L = dmpze) side arms. 3 or 4 shows a 2D (6,3) wave-like layer in which [Cu(6)(mu-CN)(6)L(2)](n) (L = dmpzpr or dmpzb) double chains are interconnected by pairs of L bridges. 5 consists of two [CuCN](n) single chains that are linked by dmpzp bridges to form a rare 1D chain with an oblong channel. has a 3D network in which the 2D [Cu(10)(mu-CN)(10)(dmpzh)(3)](n) layers are interconnected by pairs of dmpzh bridges. In addition, the photoluminescent properties of 1-6 in the solid state at ambient temperature were investigated.

References

Nov 29, 2001·Journal of the American Chemical Society·F M TabellionP J Stang
Oct 2, 2002·Inorganic Chemistry·Simon J HibbleSharon G Eversfield
Jun 13, 2003·Nature·Omar M YaghiJaheon Kim
Oct 16, 2003·Journal of the American Chemical Society·Jian-Ping LangBrendan F Abrahams
Mar 17, 2004·Angewandte Chemie·C N R RaoR Vaidhyanathan
Apr 29, 2004·Angewandte Chemie·Susumu KitagawaShin-ichiro Noro
Sep 16, 2004·Chemical Communications : Chem Comm·Raquel GiménezJosé Luis Serrano
Jun 7, 2005·Inorganic Chemistry·Xi LiuJin-Shun Huang
Aug 2, 2006·Inorganic Chemistry·Frédéric ThébaultMartin Schröder
Mar 5, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Mei-Ling ChengJian-Ping Lang
Apr 23, 2009·Chemical Society Reviews·Mohamedally Kurmoo
May 26, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Yu-Jian HuangJian-Ping Lang
Oct 8, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Ling-Ling LiJian-Ping Lang
Apr 17, 2001·Angewandte Chemie·Frank M TabellionPeter J Stang

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Citations

Jan 23, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Feng MaNai-Xuan Li
Jan 24, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Li ZhangDian-Zeng Jia

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