Crossover among structural motifs in Pd-Au nanoalloys

Physical Chemistry Chemical Physics : PCCP
Beien ZhuC Mottet

Abstract

The crossovers among the most abundant structural motifs (icosahedra, decahedra and truncated octahedra) of Pd-Au nanoalloys have been determined theoretically in a size range between 2 and 7 nm and for three compositions equivalent to Pd3Au, PdAu and PdAu3. The chemical ordering and segregation optimisation are performed via Monte Carlo simulations using semi-empirical tight-binding potentials fitted to ab initio calculations. The chemical configurations are then quenched via molecular dynamic simulations in order to compare their energy and characterize the equilibrium structures as a function of the cluster size. For the smaller sizes (of around 300 atoms and fewer) the structures are also optimized at the electronic level within ab initio calculations in order to validate the semi-empirical potential. The predictions of the crossover sizes for the nanoalloys cannot be simply extrapolated from the crossover of the pure nanoparticles but imply stress release phenomena related to the size misfit between the two metals. Indeed, alloying extends the range of stability of the icosahedron beyond that of the pure systems and the energy differences between decahedra and truncated octahedra become asymptotic, around the sizes of 5-6 ...Continue Reading

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Citations

Aug 24, 2016·Physical Chemistry Chemical Physics : PCCP·Paul C JenningsTejs Vegge
Feb 19, 2019·Physical Chemistry Chemical Physics : PCCP·Lei DengWangyu Hu
Jan 28, 2021·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Alexis Front, Christine Mottet

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