PMID: 9161011Jun 1, 1997Paper

Crystal structure and characterization of the bismuth(III) compound with quinolone family member (ciprofloxacin). Antibacterial study

Journal of Inorganic Biochemistry
Iztok TurelN Bukovec

Abstract

Two bismuth(III) compounds of ciprofloxacin (cf) were synthesized. The crystal structure of one--(cfH2) (cfH) [BiCl6].2H2O (cfH2 = doubly protonated molecule of cf, cfH = protonated molecule of cf)--is presented and discussed. The compound crystallizes in the monoclinic space group P 21/c with a = 17.758(4), b = 7.600(10), c = 31.908(6) A, beta = 101.03(2)0, Z = 4. The charge of the isolated hexachlorobismuthate(III) anions is compensated with protonated of molecules (ionic interactions). One of the cf molecules is protonated at carbonyl oxygen O(1) and nitrogen N(24) of the piperazine residue, and the other at N(24) only. Two water molecules participate in the hydrogen bond network. Antimicrobial activity of this compound was tested against different microorganisms. The results of TG and FT-IR measurements are also included.

Citations

Oct 3, 2014·Bioinorganic Chemistry and Applications·Anamika DebnathDhanraj T Masram
Sep 25, 2014·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Donal M Keogan, Darren M Griffith
Sep 14, 2013·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Valentina Uivarosi
Jan 29, 2011·Journal of Enzyme Inhibition and Medicinal Chemistry·M N PatelVasudev R Thakkar
Dec 19, 2006·International Journal of Pharmaceutics·Anwar R ShaikhMange Ram Yadav
Mar 13, 2010·Journal of Biomedical Materials Research. Part B, Applied Biomaterials·Maryam BanoeeAhmad R Shahverdi
Jun 14, 2016·Journal of Photochemistry and Photobiology. B, Biology·Qiang WeiLianzhi Li
Aug 7, 2009·Bioinorganic Chemistry and Applications·Saeed ArayneM Ahmed Mesaik
Oct 28, 2008·Journal of Enzyme Inhibition and Medicinal Chemistry·M N PatelV R Thakkar
Mar 27, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·George Psomas, Dimitris P Kessissoglou
Feb 17, 2021·The Journal of Physical Chemistry Letters·Binbin SuZhiguo Xia
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