Crystal structure of {2-methyl-2-[(pyridin-2-yl-meth-yl)amino]-propan-1-ol-κ3N ,N ',O }bis-(nitrato-κO )copper(II) from synchrotron data

Acta Crystallographica. Section E, Crystallographic Communications
Jong Won ShinDohyun Moon

Abstract

The title compound, [Cu(NO3)2(C10H16N2O)], has been synthesized and characterized by synchrotron single-crystal diffraction at 100 K. The CuII ion has a distorted square-pyramidal coordination geometry with two N and one O atoms of the C10H16N2O ligand and one nitrate anion in the equatorial plane and another nitrate anion at the axial position. The equatorial Cu-N and Cu-O bond lengths are in the range 1.9608 (14)-2.0861 (15) Å, which are shorter than the axial Cu-Onitrate bond length [2.1259 (16) Å]. In the crystal, mol-ecules are linked via inter-molecular N-H⋯O and O-H⋯O hydrogen bonds, forming a sheet structure parallel to the bc plane. The sheets are further linked through a face-to-face π-π inter-action [centroid-centroid distance = 3.994 (1) Å]. Weak inter-molecular C-H⋯O inter-actions are also observed in the sheet and between adjacent sheets.

References

May 31, 2013·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Simon ParsonsTrixie Wagner
Jan 24, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Jong Won ShinKil Sik Min
Jul 18, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Y Y Chia, M G Tay
Dec 30, 2014·Acta Crystallographica. Section A, Foundations and Advances·George M Sheldrick
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick
Dec 25, 2015·Journal of Synchrotron Radiation·Jong Won ShinDohyun Moon
Apr 7, 2016·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Colin R GroomSuzanna C Ward
Aug 10, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jong Won ShinKil Sik Min
Oct 18, 2016·Acta Crystallographica. Section E, Crystallographic Communications·Jong Won ShinDohyun Moon
Mar 18, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Jing LiuXian-He Bu

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Acta Crystallographica. Section E, Structure Reports Online
Yi-Han TanHoong-Kun Fun
Acta Crystallographica. Section E, Structure Reports Online
Rengao ZhaoJikun Li
Acta Crystallographica. Section E, Structure Reports Online
Yaru LiuChuan Zhang
© 2022 Meta ULC. All rights reserved