Crystal structure of bis-(diiso-propyl-ammonium) cis -di-iodido-bis-(oxolato-κ2O1 ,O2 )stannate(IV)

Acta Crystallographica. Section E, Crystallographic Communications
Bougar SarrYoann Rousselin

Abstract

In the title compound, (iPr2NH2)2[SnI2(C2O4)2], which was prepared by reacting ( i Pr2NH2+)2·C2O42- with SnI4 in a 2:1 molar ratio in a mixed ethanol-aceto-nitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N-H⋯O and bifurcated N-H⋯(O,O) hydrogen bonds, generating [10-1] chains.

References

Feb 21, 2013·Acta Crystallographica. Section E, Structure Reports Online·Yaya SowGabriele Kociok-Köhn
Jan 24, 2014·Acta Crystallographica. Section E, Structure Reports Online·Modou SarrHélène Cattey
May 16, 2014·Acta Crystallographica. Section E, Structure Reports Online·Martin Reichelt, Hans Reuter
Dec 30, 2014·Acta Crystallographica. Section A, Foundations and Advances·George M Sheldrick
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick
Apr 7, 2016·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Colin R GroomSuzanna C Ward

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