Crystal structure of (E )-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene

Acta Crystallographica. Section E, Crystallographic Communications
Anthony LindenHeinz Heimgartner

Abstract

The title compound, [Fe2(C5H5)2(C20H14O2)], is the product of a new synthetic route towards tetra-aryl/hetaryl-substituted ethenes that reduces the occurrence of side-products. In the crystal, the mol-ecule is centrosymmetric and the cyclo-penta-dienyl (Cp) rings are nearly coplanar and aligned slightly closer to a staggered conformation than to an eclipsed one. The ethene plane is tilted by 32.40 (18)° with respect to that of the substituted Cp ring and by 63.19 (19)° with respect to that of the furan ring. C-H⋯π inter-actions link the mol-ecules into a three-dimensional supramolecular framework.

References

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Sep 29, 2009·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Elena Ivanovna KlimovaMarcos Martinez Garcia
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Dec 30, 2014·Acta Crystallographica. Section A, Foundations and Advances·George M Sheldrick
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Methods Mentioned

BETA
X-ray
column chromatography

Software Mentioned

QATDAT
AMODIP
AMODOV
IBAXAM
QATDEX
AMODUB
ACUVAV

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