Crystal structure of hexa-kis-(dimethyl sulfoxide-κO )cobalt(II) bis-[tri-chlorido-(quinoline-κN )cobaltate(II)

Acta Crystallographica. Section E, Crystallographic Communications
Tyler K BresciaRita K Upmacis

Abstract

There are few reports that describe crystal structures of compounds containing cobalt complexed to either dimethyl sulfoxide (Me2SO) or quinoline (C9H7N). The title compound, [Co(C2H6OS)6][CoCl3(C9H7N)]2, is a cobalt salt in which the metal ion is complexed to both Me2SO and quinoline. In particular, we observed that anhydrous cobalt(II) chloride reacts with quinoline in Me2SO to form a salt that is to be formulated as [CoII(Me2SO)6]2+{[CoIICl3quinoline]2-}. The CoII atom in the cation portion of this mol-ecule lies on a inversion center and is bound to the O atoms of six Me2SO moieties in an octa-hedral configuration, while the CoII atom in the anion is attached to three chloride ligands and one quinoline moiety in a tetra-hedral arrangement.

References

Feb 20, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Lei YangRobert P Houser
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
Jan 1, 2009·Acta Crystallographica. Section E, Structure Reports Online·Qiuhong Li, Seik Weng Ng
Jan 1, 2010·Acta Crystallographica. Section E, Structure Reports Online·Marko HapkeAnke Spannenberg
Feb 22, 2012·Acta Crystallographica. Section E, Structure Reports Online·Kwang Ha
Aug 2, 2012·Acta Crystallographica. Section C, Crystal Structure Communications·William RavenUlli Englert
Jul 31, 2014·European Journal of Medicinal Chemistry·Obaid AfzalSandhya Bawa
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick
May 9, 2015·Chemical Society Reviews·Gellért SiposReto Dorta
Apr 7, 2016·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Colin R GroomSuzanna C Ward

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