Crystallographic and spectroscopic characterization of a mixed actinide-lanthanide carbide cluster stabilized inside an Ih (7)-C80 fullerene cage

Chemical Communications : Chem Comm
Xiaomeng LiNing Chen

Abstract

A mixed actinide-lanthanide cluster fullerene, Sc2UC@Ih(7)-C80, was isolated and fully characterized. For the first time, the single crystal X-ray crystallographic analysis confirms a novel actinide-lanthanide cluster Sc2UC stabilized inside an Ih(7)-C80 cage. Moreover, the U[double bond, length as m-dash]C double bond distance is 2.01 Å, the shortest U[double bond, length as m-dash]C bond confirmed by crystallography so far.

References

Oct 15, 2005·Chemistry : a European Journal·Shangfeng Yang, Lothar Dunsch
May 16, 2008·Journal of the American Chemical Society·Ivan InfanteGustavo E Scuseria
Dec 17, 2011·Inorganic Chemistry·Karah E KnopeChristopher L Cahill
Dec 12, 2012·Inorganic Chemistry·Steven StevensonAlan L Balch
May 3, 2013·Chemical Reviews·Alexey A PopovLothar Dunsch
Dec 10, 2015·Journal of the American Chemical Society·Tao WeiShangfeng Yang
Mar 1, 2016·Inorganic Chemistry·Ginger E SigmonPeter C Burns
Jul 7, 2017·Chemical Society Reviews·Shangfeng YangFei Jin
Jan 30, 2018·Journal of the American Chemical Society·Xingxing ZhangNing Chen
Jul 18, 2018·Nature Communications·Xingxing ZhangNing Chen

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