Cu-catalyzed oxidative Povarov reactions between N-alkyl N-methylanilines and saturated oxa- and thiacycles

Chemical Communications : Chem Comm
Rahul Kisan KawadeRai-Shung Liu

Abstract

Cu-catalyzed oxidative Povarov reactions between N,N-dialkylanilines and saturated oxa- or thiacycles with tert-butyl hydroperoxide (TBHP) are described; notably, the reactions use neither [4π] nor [2π]-motifs as the initial reagents. The use of cheap alkane-based substances as building units is of mechanistic and practical interest as two inert sp(3) C-H bonds are activated.

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Citations

Oct 7, 2016·Chemical Communications : Chem Comm·Congde HuoFengjuan Chen
Nov 13, 2018·Chemical Communications : Chem Comm·Rongkui SuJin-Heng Li
Oct 26, 2018·Chemistry : a European Journal·Shuya LiuYao Wang
Oct 4, 2019·Organic & Biomolecular Chemistry·Jia LiYijian Rao
Nov 11, 2016·Beilstein Journal of Organic Chemistry·David R ChisholmAndrew Whiting
Sep 12, 2018·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Xiang WuYou-Gui Li
Sep 12, 2019·Organic Letters·Yue-Hua WuJian-Yi Chi
Dec 21, 2017·Journal of the American Chemical Society·Yong LuoZhaomin Hou

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