Current trends and future challenges in the experimental, theoretical and computational analysis of intervalence charge transfer (IVCT) transitions

Chemical Society Reviews
Deanna M D'Alessandro, F Richard Keene

Abstract

Mixed-valence chemistry has a long and rich history which is characterised by a strong interplay of experimental, theoretical and computational studies. The intervalence charge transfer (IVCT) transitions generated in dinuclear mixed-valence species (particularly of ruthenium and osmium) have received considerable attention in this context, as they provide a powerful and sensitive probe of the factors which govern electronic delocalisation and the activation barrier to intramolecular electron transfer. This tutorial review discusses classical, semi-classical and quantum mechanical theoretical treatments which have been developed over the past 35 years for the analysis of IVCT absorption bands. Particular attention is drawn to the applicability of these models for the analysis of mixed-valence complexes which lie between the fully localised (Class II) and delocalised (Class III) limits in the "localised-to-delocalised" (Class II-III) regime. A clear understanding of the complex interplay of inter- and intramolecular factors which influence the IVCT process is crucial for the design of experimental studies to probe the localised-to-delocalised regime and in guidance of the development of appropriate theoretical models.

Citations

Apr 5, 2012·Journal of the American Chemical Society·Russell C PrattT Daniel P Stack
Nov 9, 2011·Proceedings of the National Academy of Sciences of the United States of America·Pratik VermaT Daniel P Stack
Jan 23, 2016·Journal of the American Chemical Society·Raúl Hernández SánchezTheodore A Betley
Sep 17, 2015·Journal of the American Chemical Society·Alexandra I GaudetteT David Harris
Aug 2, 2015·Journal of the American Chemical Society·Raúl Hernández SánchezTheodore A Betley
Aug 4, 2016·Inorganic Chemistry·Hangjuan RenCharles Christopher Sorrell
Jan 28, 2017·Inorganic Chemistry·Susanne DammersThorsten Glaser
Jun 22, 2017·Inorganic Chemistry·Lu ChenChun Y Liu
Jun 27, 2017·Journal of the American Chemical Society·Shashi Bhushan SinhaRobert H Crabtree
Sep 14, 2007·Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences·Javier J ConcepcionReginaldo C Rocha
May 28, 2019·Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences·Ryuichi MuraseDeanna M D'Alessandro
Jul 15, 2020·The Journal of Biological Chemistry·H Diessel DuanAnne-Frances Miller
Aug 6, 2020·The Journal of Chemical Physics·M G VelardeE G Wilson
Feb 6, 2021·Inorganic Chemistry·Lara CancelaJuan C Vidal
Aug 10, 2021·Journal of the American Chemical Society·Ebin Sebastian, Mahesh Hariharan
Apr 18, 2017·Journal of the American Chemical Society·Jacob B GeriNathaniel K Szymczak
Aug 28, 2019·Journal of the American Chemical Society·Chi-Yun LinSteven G Boxer
Jan 18, 2018·Journal of the American Chemical Society·Max M HansmannGuy Bertrand
Aug 15, 2017·Chemical Reviews·Carlito S PonsecaVilly Sundström
Sep 13, 2019·Journal of the American Chemical Society·Amela ArnoldLouise A Berben
May 5, 2018·Journal of the American Chemical Society·Carol HuaDeanna M D'Alessandro
Jul 21, 2017·Inorganic Chemistry·Ryuichi MuraseAshley L Sutton
May 16, 2020·Journal of the American Chemical Society·Gemma Kate GransburyColette Boskovic
Nov 8, 2018·Journal of the American Chemical Society·Raúl Hernández Sánchez, Theodore A Betley
Jul 31, 2019·Inorganic Chemistry·Bruno M Aramburu-TrošeljAlejandro Cadranel
Oct 24, 2017·Inorganic Chemistry·Mary Anne ManumpilHemamala I Karunadasa
May 8, 2018·Journal of the American Chemical Society·Eric J PiechotaGerald J Meyer
Aug 14, 2020·Journal of the American Chemical Society·Ryan Patrick Coll, Kim R Dunbar

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.