Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes.

Inorganic Chemistry
Matthew AsayGuy Bertrand

Abstract

The 3-(triphenylphosphonio)-N-(2,6-diisopropylphenyl)pyrrole reacts with 2 equiv of methyllithium to afford a lithium adduct in which a cyclic (amino)[bis(ylide)]carbene, a novel type of NHC, acts as a 1,4-bidentate ligand via the carbene center and the exocyclic ylidic carbon. This species readily undergoes transmetalation reactions, which allows for the synthesis of a variety of transition-metal complexes.

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Citations

Dec 17, 2008·Chemical Communications : Chem Comm·Junji KobayashiTakayuki Kawashima
Oct 13, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Priyam BharadwazAshwini K Phukan
Jan 9, 2016·Chemistry : a European Journal·Lingbing KongRei Kinjo
Jun 30, 2015·Chemistry : a European Journal·Bitupon Borthakur, Ashwini K Phukan
Sep 2, 2011·Angewandte Chemie·Matthew AsayMatthias Driess
Aug 16, 2014·Chemistry : a European Journal·Florie LavigneAntoine Baceiredo
Sep 17, 2013·Angewandte Chemie·Elisa González-FernándezManuel Alcarazo
Sep 25, 2008·Angewandte Chemie·Alois FürstnerChristian W Lehmann
Aug 3, 2010·Angewandte Chemie·David GauAntoine Baceiredo
Sep 14, 2010·Angewandte Chemie·Mohand MelaimiGuy Bertrand
Feb 16, 2016·Beilstein Journal of Organic Chemistry·Diego M AndradaGernot Frenking
Mar 25, 2016·Journal of Computational Chemistry·Bitupon BorthakurAshwini K Phukan
Feb 7, 2015·Angewandte Chemie·Javier RuizJuan Francisco Van der Maelen
May 16, 2018·Chemistry, an Asian Journal·Yves Canac
Nov 9, 2019·Organic & Biomolecular Chemistry·Morgan M BurgoyneC Adam Dyker
Apr 15, 2010·Angewandte Chemie·Hans BrunsManuel Alcarazo
Feb 16, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Henning SteinertViktoria H Gessner
Aug 23, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Chandrakanta DashH V Rasika Dias
Apr 17, 2009·Chemical Reviews·Joan VignolleDidier Bourissou
Aug 17, 2017·Journal of the American Chemical Society·Wen-Ching ChenTiow-Gan Ong

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