Cyclo-pnicta-triazanes: biradicaloids or zwitterions?

Journal of the American Chemical Society
Alexander HinzJan-Martin Wolter

Abstract

Bulky triazenides were utilized in the reaction with pnictogen(III) chlorides (ECl3, E = P, As, Sb, and Bi) yielding triaza-pnicta-butene analogues of the type R-N═N-N(R)-ECl2 (R = Ter = 2,6-bis(2,4,6-trimethylphenyl)phenyl). Subsequent reduction of these dichloro-species afforded unprecedented four-membered group 15 heterocycles [E(μ-NTer)2N] bearing one dicoordinate pnictogen and nitrogen atom. These N3E rings represent species at the borderline between singlet biradicaloids and zwitterions with diminished reactivity compared to known singlet biradicaloids. The N3P compound could be identified, while N3As and N3Sb species as well as the precursor compounds were fully characterized.

References

Mar 9, 2002·Science·David ScheschkewitzGuy Bertrand
Feb 5, 2004·Journal of the American Chemical Society·Hideki AmiiGuy Bertrand
Jun 19, 2004·The Journal of Organic Chemistry·Wei Quan Tian, Yan Alexander Wang
Aug 2, 2006·Inorganic Chemistry·Hyui Sul Lee, Mark Niemeyer
Jan 3, 2007·Inorganic Chemistry·Shaun P GreenAndreas Stasch
Mar 28, 2007·Chemical Society Reviews·Maravanji S BalakrishnaTristram Chivers
Jul 16, 2008·Angewandte Chemie·Shigekazu ItoAnthony J Arduengo
Sep 18, 2009·Journal of the American Chemical Society·Xinping WangPhilip P Power
Oct 27, 2009·Chemistry : a European Journal·Pekka Pyykkö, Michiko Atsumi
Dec 18, 2009·Inorganic Chemistry·Hyui Sul Lee, Mark Niemeyer
Sep 16, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Fabian ReissNico Weding
Mar 23, 2011·Chemical Communications : Chem Comm·Allison L BrazeauPaul J Ragogna
Jul 23, 2011·Journal of the American Chemical Society·Katsuhiko TakeuchiAkira Sekiguchi
Aug 23, 2011·Angewandte Chemie·Torsten BeweriesAlexander Villinger
Jan 16, 2013·Angewandte Chemie·Serhiy DemeshkoAlexander Villinger
Mar 14, 2013·Journal of Computational Chemistry·Eric D GlendeningFrank Weinhold
Jul 26, 2013·Chemical Reviews·Manabu Abe
Oct 1, 2014·Chemistry : a European Journal·Alexander HinzAlexander Villinger

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Citations

Mar 21, 2016·Chemistry : a European Journal·Iva VránováLibor Dostál
Aug 25, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexander HinzAlexander Villinger
Dec 17, 2017·Chemistry : a European Journal·Zhongshu LiXiaodan Chen
Nov 15, 2017·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Shigekazu Ito
Jan 12, 2016·Chemistry : a European Journal·Jianhuai YeWaldemar Adam
Jun 14, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jan VránaLibor Dostál
Sep 6, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Axel Schulz
Feb 12, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Alasdair I McKay, Marcus L Cole
Jul 30, 2019·Chemistry : a European Journal·Monika KořenkováLibor Dostál
Oct 8, 2019·Chemistry : a European Journal·Jonas BresienAlexander Villinger
Apr 15, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Matthew R GytonAlasdair I McKay
Apr 21, 2016·Angewandte Chemie·Alexander Hinz, Jose M Goicoechea
Aug 20, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Anthony R LeverettAlasdair I McKay
Jul 6, 2016·Chemistry : a European Journal·Alexander HinzAlexander Villinger
Jun 17, 2020·Chemical Reviews·Owen T O'Sullivan, Michael J Zdilla
Apr 21, 2021·Physical Chemistry Chemical Physics : PCCP·Tim VölzerJonas Bresien
Aug 10, 2021·Chemical Society Reviews·Kei Ota, Rei Kinjo
Aug 25, 2020·The Journal of Organic Chemistry·Anatoliy MarchenkoAleksandr Kostyuk
Sep 28, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Jan VránaAleš Růžička

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