Cycloparaphenylene as a molecular porous carbon solid with uniform pores exhibiting adsorption-induced softness

Chemical Science
Hirotoshi SakamotoKenichiro Itami

Abstract

The molecular carbon nanoring, cycloparaphenylene (CPP), is fascinating as a new class of carbonaceous porous solids with the uniform structure of an all-benzene surface. We explored the feasibility of [12]CPP as a carbon-based porous material and uncovered its unique adsorption properties due to its shape and highly nonpolar surface. Unlike other porous carbon solids, [12]CPP shows stepwise adsorption behaviors sensitive to the functionalities of the guest molecules. In situ powder X-ray diffraction and infrared spectra provided insights into how [12]CPP accommodates the guest molecules with structural deformation retaining its structural periodicity during the whole adsorption process, which exemplifies that this molecular nanoring represents an unprecedented carbon-based soft porous solid.

References

Aug 9, 2003·Nature Materials·Yury GogotsiMichel W Barsoum
Feb 24, 2006·Chemical Communications : Chem Comm·Fabrice O M GaslainJoël Patarin
Oct 26, 2007·The Journal of Organic Chemistry·Chun Zhang, Chuan-Feng Chen
Dec 6, 2008·Journal of the American Chemical Society·Ramesh JastiCarolyn R Bertozzi
Jul 10, 2009·Angewandte Chemie·Hiroko TakabaKenichiro Itami
Oct 27, 2009·Nature Materials·Tomokazu TozawaAndrew I Cooper
Dec 17, 2009·Angewandte Chemie·Shigeru YamagoTakahiro Iwamoto
Dec 3, 2010·Nature Chemistry·Satoshi HorikeSusumu Kitagawa
Jan 13, 2011·Chemical Physics Letters·Ramesh Jasti, Carolyn R Bertozzi
Feb 2, 2011·Journal of the American Chemical Society·Sachie HashimotoKatsumi Kaneko
Mar 4, 2011·Angewandte Chemie·Yasutomo SegawaKenichiro Itami
May 6, 2011·Journal of the American Chemical Society·Takahiro IwamotoShigeru Yamago
May 27, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Tomonori Ohba, Katsumi Kaneko
Jun 15, 2011·Journal of the American Chemical Society·Koki UritaKatsumi Kaneko
Aug 13, 2011·Chemistry : a European Journal·Tamoghna MitraAndrew I Cooper
Sep 1, 2011·Physical Chemistry Chemical Physics : PCCP·Yun LongKeith E Gubbins
Sep 15, 2011·Journal of the American Chemical Society·Thomas J SistoRamesh Jasti
Jan 31, 2012·Angewandte Chemie·Jianlong Xia, Ramesh Jasti
Mar 24, 2012·Organic & Biomolecular Chemistry·Yasutomo SegawaKenichiro Itami
Jun 20, 2012·Organic Letters·Eiichi KayaharaShigeru Yamago
Jun 29, 2012·Angewandte Chemie·Andrew I Cooper
Jul 19, 2012·The Journal of Organic Chemistry·Evan R DarziRamesh Jasti
Jul 19, 2012·Chemistry : a European Journal·Michael Mastalerz
Aug 2, 2012·Journal of the American Chemical Society·Akihito ShigematsuHiroshi Kitagawa
Sep 28, 2012·Physical Chemistry Chemical Physics : PCCP·Mamoru FujitsukaTetsuro Majima
Feb 22, 2013·Angewandte Chemie·Antonio AvellanedaChristian J Doonan
Apr 9, 2013·Angewandte Chemie·Alexander V ZabulaMarina A Petrukhina
Jun 22, 2013·Nature Chemistry·Haruka OmachiKenichiro Itami
Jun 26, 2013·Organic Letters·Shunpei HitosugiHiroyuki Isobe
Jul 16, 2013·Nature Communications·Toshihiko FujimoriKatsumi Kaneko
Oct 11, 2013·Chemistry : a European Journal·Takahiro IwamotoShigeru Yamago
Oct 30, 2013·Nature Communications·Eiichi KayaharaShigeru Yamago
Nov 21, 2013·Angewandte Chemie·Eiichi KayaharaShigeru Yamago
Dec 7, 2013·Chemical Communications : Chem Comm·Friederike SibbelKenichiro Itami
Dec 18, 2013·Chemical Society Reviews·Gang Zhang, Michael Mastalerz
Jan 24, 2014·Angewandte Chemie·Florian E GollingKlaus Müllen
Jan 28, 2014·Journal of the American Chemical Society·Eiichi KayaharaShigeru Yamago
Mar 13, 2014·Angewandte Chemie·Yusuke NakanishiHisanori Shinohara
May 23, 2014·Nature·Ryotaro Matsuda
Jun 10, 2014·Proceedings of the National Academy of Sciences of the United States of America·Sota SatoHiroyuki Isobe
Jun 12, 2014·Organic Letters·Shunpei HitosugiHiroyuki Isobe
Sep 17, 2014·Chemistry : a European Journal·Takahiro IwamotoShigeru Yamago
Nov 2, 2014·Journal of the American Chemical Society·Katsuma MatsuiKenichiro Itami

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Citations

Jun 14, 2019·Angewandte Chemie·Youzhi Xu, Max von Delius
Mar 4, 2020·Chemical Communications : Chem Comm·Gavin A CraigShuhei Furukawa
Apr 26, 2019·Chemistry : a European Journal·Yearin ByunAli Coskun
Aug 24, 2019·Scientific Reports·Manabu HoshinoDaisuke Hashizume
Apr 30, 2017·Chemical Science·Keishu OkadaKenichiro Itami
Nov 26, 2016·Chemistry : a European Journal·Teng-Hao ChenOgnjen Š Miljanić
Jun 28, 2018·Chemical Communications : Chem Comm·Sarah N SpisakMarina A Petrukhina
Sep 25, 2019·Research : a Science Partner Journal·Huang TangXiqun Jiang
Nov 12, 2019·Journal of the American Chemical Society·Youzhi XuMax von Delius
Mar 29, 2019·The Journal of Organic Chemistry·Hongyan ZhaoXiaoyu Yan
Jul 24, 2018·Journal of the American Chemical Society·Guillaume PovieKenichiro Itami
Jun 15, 2019·ACS Applied Materials & Interfaces·Li Zhi GuanFrancisco Del Monte
Oct 19, 2019·The Journal of Organic Chemistry·Jeff M Van RadenRamesh Jasti

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