Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base

Angewandte Chemie
Holger BraunschweigQing Ye

Abstract

An electron-rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 Lewis acids using both its boron and nitrogen sites. The hard Lewis acid AlCl3 binds through a nitrogen atom of the Lewis base, while softer Lewis acids GaX3 (Cl, Br, I) bind at the boron atom. The latter are the first noncluster Lewis adducts between a boron-centered Lewis base and a main-group Lewis acid.

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Citations

Jun 17, 2016·Journal of the American Chemical Society·Lingbing KongRei Kinjo
Jan 20, 2017·Journal of the American Chemical Society·Holger BraunschweigQing Ye
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Oct 2, 2021·Chemistry : a European Journal·Merle ArrowsmithHolger Braunschweig

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