Deep-ultraviolet nonlinear optical crystals: Ba3P3O10X (X = Cl, Br)

Journal of the American Chemical Society
Peng YuLing Chen

Abstract

Deep-ultraviolet nonlinear optical (deep-UV NLO) crystals are of worldwide interest for the generation of coherent light with wavelength below 200 nm by the direct second-harmonic generation (SHG) output from solid-state lasers. The unprecedented deep-UV NLO phosphates representing their own structure types, Ba3P3O10Cl (BPOC), Ba3P3O10Br (BPOB), have been discovered, which display moderate powder SHG intensities in type I phase matchable behaviors with a short UV cutoff edge of 180 nm (measured by a single crystal, one of the shortest values among phosphates to date). Insightfully, the geometry and polarization of the C1-P3O10(5-) building unit are affected by the crystal packing. DFT calculations and cutoff energy dependent SHG coefficient analyses reveal that the SHG origin is from the cooperation of asymmetric C1-P3O10(5-) anion, Ba(2+) cation, and Cl(-)/Br(-) anion.

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Citations

Dec 22, 2015·Journal of the American Chemical Society·Hongwei YuP Shiv Halasyamani
Feb 19, 2016·Journal of the American Chemical Society·Sangen ZhaoJunhua Luo
Mar 26, 2016·Journal of the American Chemical Society·Hongwei YuP Shiv Halasyamani
Jul 7, 2015·Journal of the American Chemical Society·Xiaoyu DongJames M Rondinelli
Jul 13, 2016·Journal of the American Chemical Society·Lin LiShilie Pan
Jan 4, 2017·Inorganic Chemistry·Yi-Gang ChenXian-Ming Zhang
Mar 16, 2017·Inorganic Chemistry·Maierhaba AbudourehemanShilie Pan
Dec 8, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Dongdong XuShilie Pan
Feb 2, 2017·Chemical Communications : Chem Comm·Bing-Hua LeiShilie Pan
Mar 25, 2015·Physical Chemistry Chemical Physics : PCCP·Fangyuan ZhangDianzeng Jia
Feb 3, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Lin LiShilie Pan
Jun 30, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Ming WenShilie Pan
Feb 11, 2015·Angewandte Chemie·Sangen ZhaoJunhua Luo
Dec 1, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Fangfang HeGuohong Zou
Feb 16, 2019·Physical Chemistry Chemical Physics : PCCP·Ruonan YinZhihua Yang
May 31, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Shujuan HanShilie Pan
Jul 3, 2019·Chemical Communications : Chem Comm·Zhiyong BaiZhoubin Lin
Oct 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Haonan LiuYicheng Wu
May 7, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Ming WenShilie Pan
Aug 11, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Wenyao ZhangShilie Pan
Mar 24, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Li-Jun ZhangLing Chen
Sep 15, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Chao WuChi Zhang
Aug 23, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun SunShilie Pan
Sep 16, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Mengmeng DingYicheng Wu
Jul 4, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Jie-Ling XieJun-Ling Song
Oct 22, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Philip NetzschHenning A Höppe

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