Dehydration of the nanoporous coordination framework ErIII[CoIII(CN)6].4(H2O): single crystal to single crystal transformation and negative thermal expansion in ErIII[CoIII(CN)6

Chemical Communications : Chem Comm
Thorsten PretschCameron J Kepert

Abstract

Desorption of bound and unbound water molecules from the nanoporous coordination framework ErIII[CoIII(CN)6].4(H2O) to form the apohost, ErIII[CoIII(CN)6], proceeds via a single crystal to single crystal transformation in which the Er(III) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.

References

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Mar 5, 2002·Inorganic Chemistry·Simon J HibbleSharon G Eversfield
Jul 23, 2003·Inorganic Chemistry·Simon J HibbleSimon M Cheyne
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Feb 9, 2006·Chemical Communications : Chem Comm·Cameron J Kepert

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Citations

Dec 18, 2009·Journal of the American Chemical Society·Anthony E PhillipsCameron J Kepert
Jun 29, 2017·Inorganic Chemistry·Stefan SuckertChristian Näther
Apr 19, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Maria-Gabriela AlexandruMiguel Julve
Jun 9, 2015·Chemical Communications : Chem Comm·Huan-Cheng HuBin Zhao
Dec 21, 2007·Angewandte Chemie·Anthony E PhillipsCameron J Kepert
Feb 24, 2011·Journal of Fluorescence·Malaichamy Ilanchelian, Ramasamy Ramaraj
Sep 29, 2012·Nephrology·Vasileios RaptisDimitrios Grekas
Oct 3, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Yen-Hsiang LiuChen-I Yang
Dec 15, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Qing ZhaoPeng Cheng
May 19, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Li-Rong GuoLi-Min Zheng
Apr 24, 2009·Journal of the American Chemical Society·Andrew L GoodwinCameron J Kepert
Aug 18, 2009·Journal of the American Chemical Society·Ann M Chippindale, Simon J Hibble

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