Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex

Dalton Transactions : an International Journal of Inorganic Chemistry
M TroseT Beweries

Abstract

The dinuclear zirconocene chloride complex 1 is a highly active precatalyst for the dehydropolymerisation of methylamine borane. Comparison with mononuclear Zr chlorides and related dinuclear complexes suggests that the nature of the bridging motif is essential for the unique reactivity of 1.

References

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Citations

Oct 20, 2018·Chemistry : a European Journal·Annie L Colebatch, Andrew S Weller
Mar 14, 2019·Chemistry : a European Journal·Estefanía Del HornoCarlos Yélamos
Mar 19, 2020·Chemical Society Reviews·Uwe Rosenthal
Dec 13, 2019·Chemical Communications : Chem Comm·Timothy M BoydAndrew S Weller
Jun 14, 2019·Chemical Science·Fabian ReißTorsten Beweries
Dec 1, 2021·Journal of the American Chemical Society·Claire N BrodieAndrew S Weller

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Methods Mentioned

BETA
X-ray
NMR
light scattering

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