Deprotonation induced ligand-to-metal electron transfer: synthesis of a mixed-valence Rh(-I,I) dinuclear compound and its reaction with dioxygen

Journal of the American Chemical Society
Cristina TejelBas de Bruin

Abstract

Treatment of bis(2-picolyl)amine (bpa) with [{Rh(nbd)(mu-OMe)}2] leads to the unexpected and unique redox asymmetric dinuclear Rh-I,Rh+I complex [{Rh(nbd)}2(bpa-2H)] (2) with a pi-coordinating imine bound to a tetrahedral low valent rhodate(-I). Mono-oxygenation of the deprotonated bpa ligand in 2 by O2 leads to the mononuclear carboxamido complex [Rh(nbd)(bpam-H)] (3) (bpam = N-(2-picolyl)picolinamide). The second O atom of O2 ends up as a hydroxo fragment in [{Rh(nbd)(mu-OH)}2].

References

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Citations

Apr 28, 2011·Inorganic Chemistry·Wojciech I DzikBas de Bruin
Apr 28, 2011·Inorganic Chemistry·Di ZhuPeter H M Budzelaar
Sep 8, 2010·Chemical Communications : Chem Comm·Nanda D PaulSreebrata Goswami
Jan 29, 2017·Chemistry : a European Journal·Laia Vilella-ArribasCristina Tejel
Feb 13, 2014·Chemistry : a European Journal·Ana M GeerCristina Tejel
Jul 28, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Dide G A Verhoeven, Marc-Etienne Moret
Jun 18, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·S AnjanaNarasimha N Murthy
Sep 25, 2014·Chemistry : a European Journal·Naina DeibelBiprajit Sarkar
Sep 13, 2018·Chemistry : a European Journal·Ana M GeerCristina Tejel
Jan 3, 2019·Chemistry : a European Journal·Marc DevillardJarl Ivar van der Vlugt
Nov 20, 2008·Chemistry : a European Journal·Cristina TejelBas de Bruin
Dec 22, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Pablo J Sanz MiguelBernhard Lippert
Nov 29, 2014·Chemistry : a European Journal·Louise A Berben
Aug 23, 2019·Chemistry : a European Journal·Paula AbrilCristina Tejel
Aug 1, 2015·Chemistry : a European Journal·Zhou TangBas de Bruin
Mar 4, 2011·Angewandte Chemie·Gregor Meier, Thomas Braun
Nov 17, 2016·Chemical Society Reviews·Addison N Desnoyer, Jennifer A Love
Sep 16, 2014·Inorganic Chemistry·Jeewantha S HewageJames R Gardinier
Aug 17, 2018·Inorganic Chemistry·Dide G A VerhoevenMarc-Etienne Moret
Oct 12, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Sinval F SousaAntonio Otavio T Patrocinio

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