Determination of fuel dialkyl ethers and BTEX in water using headspace solid-phase microextraction and gas chromatography-flame ionization detection

Journal of Chromatography. a
Idoia ArambarriEsmeralda Millán

Abstract

A simple procedure for the determination of methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), ethyl butyl ether (EBE), tert-amyl methyl ether (TAME), benzene, toluene, ethylbenzene, and xylenes (BTEX) in water using headspace (HS) solid-phase microextraction (HS-SPME) was developed. The analysis was carried out by gas chromatography (GC) equipped with flame ionization detector (FID) and 100% dimethylpolysiloxane fused capillary column. A 2 Plackett-Burman design for screening and a central composite design (CCD) for optimizing the significant variables were applied. Fiber type, extraction temperature, sodium chloride concentration, and headspace volume were the significant variables. A 65 microm poly(dimethylsiloxane)-divinylbenzene (PDMS-DVB) SPME fiber, 10 degrees C, 300 g/l, and 20 ml of headspace (in 40 ml vial) were respectively chosen for the best extraction response. An extraction time of 10 min was enough to extract the ethers and BTEX. The relative standard deviation (R.S.D.) for the procedure varied from 2.6 (benzene) to 8.5% (ethylbenzene). The method detection limits (MDLs) found were from 0.02 (toluene, ethylbenzene, and xylenes) to 1.1 microg/l (MTBE). The optimized method was applied to the analysis ...Continue Reading

Associated Proceedings Papers

Nov 2, 2020·Norizah Abd. KarimZ. Nur Aimi Nadhirah

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Citations

Sep 27, 2002·Environmental Science & Technology·Christine AchtenRegine Gihr
Apr 2, 2003·Chemosphere·Joseph L ZuccarelloDavid B Green

Related Concepts

Miller Dieker Syndrome
Ethers for general anesthesia
Ethyl tert-butyl ether
poly(dimethylsiloxane-divinylbenzene)
Ethylbenzene
Ethers
Benzene
Etherum, ether, Homeopathic preparation
Petroleum
Dimethylsiloxanes

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