Determination of inter-ionic and intra-ionic interactions in a monofluorinated imidazolium ionic liquid by a combination of X-ray crystallography and NOE NMR spectroscopy

Magnetic Resonance in Chemistry : MRC
Yves LingscheidRalf Giernoth

Abstract

We report the very first application of a Transient 1D 1 H{19 F} NOE NMR experiment in neat ionic liquids. In comparison with classical 2D HOESY NMR spectroscopy, a substantial reduction in measurement time is gained with comparable quality and information content of the spectra. In combination with classical X-ray crystallography, we have applied this technique for the determination of inter-ionic distances (i.e. probabilities of presence) utilizing an ionic liquid containing a monofluorinated imidazolium cation. Copyright © 2017 John Wiley & Sons, Ltd.

References

Oct 5, 1973·The Journal of Organic Chemistry·K L Kirk, L A Cohen
Jun 21, 2003·The Journal of Organic Chemistry·J T Gerig
Feb 24, 2006·The Journal of Physical Chemistry. B·José N A Canongia Lopes, Agílio A H Pádua
Jul 21, 2006·The Journal of Physical Chemistry. B·Crestina S ConsortiJairton Dupont
Sep 4, 2008·Journal of the American Chemical Society·Huanyu ZhaoRonald Breslow
Oct 18, 2011·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Yves LingscheidRalf Giernoth
Apr 6, 2012·Journal of Applied Crystallography·Christian B HübschleBirger Dittrich
Jun 19, 2013·Angewandte Chemie·Sonja GablHermann Weingärtner
Dec 30, 2014·Acta Crystallographica. Section A, Foundations and Advances·George M Sheldrick
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick
Feb 19, 2015·Physical Chemistry Chemical Physics : PCCP·Daniel Braun, Othmar Steinhauser
Jun 2, 2015·Chemical Reviews·Robert HayesRob Atkin

❮ Previous
Next ❯

Citations

May 3, 2018·Physical Chemistry Chemical Physics : PCCP·Pierre-Alexandre MartinMichaël Deschamps

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
Yves LingscheidRalf Giernoth
Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
Lena Cardoso, Nuno M Micaelo
© 2022 Meta ULC. All rights reserved