Development of organic solvents-free mode of solidification of floating organic droplet-based dispersive liquid-liquid microextraction for the extraction of polycyclic aromatic hydrocarbons from honey samples before their determination by gas chromatography-mass spectrometry.

Journal of Separation Science
Farzin FazaieliAli Mohebbi

Abstract

In this study, a green mode of solidification of floating organic droplet-based dispersive liquid-liquid microextraction has been developed for the extraction of 16 polycyclic aromatic hydrocarbons from honey samples before their determination by gas chromatography-mass spectrometry. In this method, an appropriate volume of menthol:decanoic acid deep eutectic solvent (as an extraction solvent) is added on a sugar cube (as a disperser agent). In the following, the cube is released into the diluted honey sample placed in a tube. After manual shaking a cloudy state is obtained as a result of dispersing the extraction solvent droplets throughout the sample solution and the analytes are extracted into them. After placing the tube in an ice bath, the droplet of the extractant is solidified on the top of the solution. This drop is taken and after dissolving in acetonitrile, an aliquot of the solution is injected into the separation system. Under optimum conditions, the suggested approach had high extraction recoveries (76-93%) and enrichment factors (380-465), low limits of detection (14-52 ng/kg) and quantification (47-173 ng/kg), and satisfactory repeatability (relative standard deviation ≤ 9%).

References

Dec 24, 2003·Journal of Agricultural and Food Chemistry·Cristina BlascoYolanda Picó
Apr 1, 2006·Journal of Chromatography. a·Mohammad RezaeeSana Berijani
Mar 28, 2007·Analytica Chimica Acta·Mohammad Reza Khalili ZanjaniJan Ake Jönsson
Jun 1, 2012·Food Additives & Contaminants. Part B, Surveillance·Behrouz AkbariGholamreza Karimi
May 9, 2014·ChemSusChem·Francisco Pena-Pereira, Jacek Namieśnik

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