Diastereoselective cyclization of a dithienylethene switch through single crystal confinement

Organic & Biomolecular Chemistry
Kingo UchidaBen L Feringa

Abstract

Upon UV irradiation of the hydrogen-bond confined crystal state of a dithienylhexafluorocyclopentene with (R)-N-phenylethylamide substituents, the photochemical cyclization reaction proceeds diastereoselectively to form the coloured, closed-ring isomer with 97% de.

References

Jan 5, 2002·Chemical Reviews·Masahiro Irie
Dec 14, 2002·Chemical Communications : Chem Comm·Seiya KobatakeMasahiro Irie
Apr 2, 2004·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Masakazu MorimotoMasahiro Irie

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Citations

Dec 5, 2018·Angewandte Chemie·Christoph JurissekStefan Hecht
Mar 9, 2013·Angewandte Chemie·Tamara C S PaceJoakim Andréasson
Sep 24, 2013·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·Tomohiro IchikawaMasahiro Irie
Apr 11, 2008·Chemical Communications : Chem Comm·Kingo UchidaBen L Feringa
Apr 11, 2008·Chemical Communications : Chem Comm·Masakazu MorimotoMasahiro Irie
Dec 18, 2020·Chemical Communications : Chem Comm·Susnata PramanikIvan Huc

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