Dicarboxylate-bridged ruthenium complexes as building blocks for molecular nanostructures

Inorganic Chemistry
Benan KilbasKay Severin

Abstract

Ruthenium complexes with bridging dicarboxylate ligands were combined with 1,2-di-4-pyridylethylene (dpe), 2,4,6-tri-4-pyridyltriazine (4-tpt), or 2,4,6-tri-3-pyridyltriazine (3-tpt) to give a tetranuclear rectangle or hexanuclear coordination cages. The cages display a trigonal-prismatic geometry, as evidenced by single-crystal X-ray crystallography. The 4-tpt-based cages are able to encapsulate polyaromatic molecules such as pyrene, triphenylene, or coronene, whereas the 3-tpt-based cages were found to be incompetent hosts for these guests.

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Citations

Mar 19, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Lin LinGuo-Xin Jin
Jan 7, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Anurag MishraKi-Whan Chi
Sep 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Laura J McCormickRussell E Morris
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Jun 4, 2014·Chemical Communications : Chem Comm·Anurag MishraKi-Whan Chi
Apr 3, 2013·Journal of the American Chemical Society·Maarten M J SmuldersJonathan R Nitschke

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