Direct Dehydrative Glycosylation of C1-Alcohols

Chemistry, an Asian Journal
Sloane O'NeillMaciej A Walczak

Abstract

Due to the central role played by carbohydrates in a multitude of biological processes, there has been a sustained interest in developing effective glycosylation methods to enable more thorough investigation of their essential functions. Among the myriad technologies available for stereoselective glycoside bond formation, dehydrative glycosylation possesses a distinct advantage given the unique properties of C1-alcohols such as straightforward preparation, stability, and a general reactivity compatible with a diverse set of reaction conditions. In this Focus Review, a survey of direct dehydrative glycosylations of C1-alcohols is provided with an emphasis on recent achievements, pervading limitations, mechanistic insights, and applications in total synthesis.

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Citations

Mar 7, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Mei-Yuan HsuCheng-Chung Wang
Jan 7, 2021·Organic & Biomolecular Chemistry·Trichada RatthachagPanuwat Padungros
Jul 1, 2020·The Journal of Organic Chemistry·Mosidur Rahaman MollaRima Thakur

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