Direct functionalization of alkyl ethers to construct hemiaminal ether skeletons (HESs)

Organic & Biomolecular Chemistry
Longyang DianYunfei Du

Abstract

Hemiaminal ether skeletons (HESs) are important backbones generally found in organic compounds. Compared to traditional functional group transformations, strategies for the C-H functionalization of alkyl ethers to construct HESs have drawn much attention in the past decade. In this review, we focus on the recent progress in developing various pathways to construct HESs via the direct functionalization of alkyl ethers, including: (a) the transition-metal-catalyzed nitrene insertion pathway, (b) the transition-metal-free organonitrenoid insertion pathway,

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Citations

Jun 25, 2019·Angewandte Chemie·Daniel Hernández-GuerraUllrich Jahn
Aug 8, 2020·Organic & Biomolecular Chemistry·André ShamsabadiVijay Chudasama
Jan 26, 2021·The Journal of Organic Chemistry·Satish G MoreGurunath Suryavanshi
Jun 3, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Pengcheng WangHuaiji Zheng
Jun 28, 2019·The Journal of Organic Chemistry·Makafui GasonooSébastien Laulhé

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Methods Mentioned

BETA
amidation

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