Direct measurement of adhesion energy of monolayer graphene as-grown on copper and its application to renewable transfer process

Nano Letters
Taeshik YoonByung Jin Cho

Abstract

Direct measurement of the adhesion energy of monolayer graphene as-grown on metal substrates is important to better understand its bonding mechanism and control the mechanical release of the graphene from the substrates, but it has not been reported yet. We report the adhesion energy of large-area monolayer graphene synthesized on copper measured by double cantilever beam fracture mechanics testing. The adhesion energy of 0.72 ± 0.07 J m(-2) was found. Knowing the directly measured value, we further demonstrate the etching-free renewable transfer process of monolayer graphene that utilizes the repetition of the mechanical delamination followed by the regrowth of monolayer graphene on a copper substrate.

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Citations

Jun 13, 2013·ACS Nano·Maria SchriverAlex Zettl
Sep 27, 2013·Proceedings of the National Academy of Sciences of the United States of America·Mir Mohammad SadeghiLi Shi
Dec 20, 2015·ACS Applied Materials & Interfaces·Minmin ZhuEdwin Hang Tong Teo
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