Direct N-formylation of nitroarenes with CO2

Chemical Communications : Chem Comm
Ni ShenJun-An Ma

Abstract

Herein we describe a straightforward N-formylation of nitroarenes with CO2 to access N-aryl formamides exclusively in the presence of iron and hydrosilane as additives. This protocol showcases a good tolerance of a wide range of nitroarenes and nitroheteroarenes.

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Citations

Jan 28, 2021·Chemical Communications : Chem Comm·Zhi-Peng BaoXiao-Feng Wu
Sep 3, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Dinesh S Barak, Sanjay Batra

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