Directing the mechanism of CO2 reduction by a Mn catalyst through surface immobilization

Physical Chemistry Chemical Physics : PCCP
James J WalshAlexander J Cowan

Abstract

Immobilization of a Mn polypyridyl CO2 reduction electrocatalyst on nanocrystalline TiO2 electrodes yields an active heterogeneous system and also significantly triggers a change in voltammetric and catalytic behaviour, relative to in solution. A combination of spectroelectrochemical techniques are presented here to elucidate the mechanism of the immobilized catalyst in situ.

References

Nov 26, 2009·Accounts of Chemical Research·Amanda J MorrisEtsuko Fujita
Oct 16, 2010·The Journal of Organic Chemistry·D Bradley G Williams, Michelle Lawton
Feb 20, 2013·Inorganic Chemistry·Jonathan M SmiejaClifford P Kubiak
Sep 11, 2014·Chemical Communications : Chem Comm·James J WalshAlexander J Cowan
Dec 17, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Jay AgarwalHenry F Schaefer Iii
Sep 17, 2015·Faraday Discussions·James J WalshAlexander J Cowan
Jan 26, 2016·Journal of the American Chemical Society·Marcel SchreierMichael Grätzel
Jan 25, 2017·Journal of the American Chemical Society·Ken T NgoJonathan Rochford

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