Discrete {Gd(III)₄M} (M = Gd(III) or Co(II)) pentanuclear complexes: a new class of metal-organophosphate molecular coolers

Dalton Transactions : an International Journal of Inorganic Chemistry
Sandeep K GuptaRamaswamy Murugavel

Abstract

The first examples of homo- and hetero-polymetallic organophosphates of gadolinium are reported. Magnetic measurements reveal a higher magnetic entropy change for the isotropic {Gd(III)5} complex (25.8 J kg(-1) K(-1)) as compared to the heterometallic {Gd(III)4Co(II)} complex (20.3 J kg(-1) K(-1)), which is attributable to a change in magnetic coupling as estimated from DFT calculations.

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Citations

Jul 2, 2016·Chemical Communications : Chem Comm·Tulika Gupta, Gopalan Rajaraman
Mar 18, 2017·Inorganic Chemistry·Sandeep K GuptaRamaswamy Murugavel
Feb 17, 2017·Chemistry : a European Journal·Sourav BiswasVadapalli Chandrasekhar
Apr 14, 2017·Chemical Communications : Chem Comm·María José Heras OjeaMark Murrie
Mar 23, 2018·Chemistry : a European Journal·Ritambhara JangirRamaswamy Murugavel
Mar 23, 2018·Chemical Communications : Chem Comm·Sandeep K Gupta, Ramaswamy Murugavel
Apr 18, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sourav BiswasVadapalli Chandrasekhar
Jun 22, 2019·Chemical Communications : Chem Comm·Kamna SharmaRamaswamy Murugavel
Feb 6, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Biswajit SantraAnukul Jana
Jul 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·L Rosado PiquerE C Sañudo
Feb 12, 2017·Inorganic Chemistry·Javeed Ahmad Sheikh, Abraham Clearfield
Dec 5, 2017·Journal of the American Chemical Society·Xiu-Ying ZhengLan-Sun Zheng

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