Donor-acceptor chemistry at heavy chalcogen centers

Inorganic Chemistry
Jason L Dutton, Paul J Ragogna

Abstract

A series of coordination complexes, where a heavy chalcogen (Se, Te) acts as the acceptor site, using a variety of electron rich Lewis bases (phosphine, imine, N-heterocyclic carbene), have been synthesized and comprehensively characterized. Each derivative is a representative example of a E-->Ch coordinative bond, characterizing an efficient E-E bond forming methodology and a systematic investigation into the coordination chemistry of the chalcogens. The complexes are susceptible to classic ligand exchange reactions, verifying the dative E-->Ch bonding motif.

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Citations

Apr 3, 2012·Inorganic Chemistry·Alfredo M Angeles-Boza, Justine P Roth
Jul 31, 2012·Inorganic Chemistry·Jonathan W DubePaul J Ragogna
Nov 21, 2013·Inorganic Chemistry·Elisa I CarreraDwight S Seferos
Dec 30, 2010·Journal of the American Chemical Society·S M Ibrahim Al-RafiaEric Rivard
Aug 21, 2013·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Anton V LonchakovAndrey V Zibarev
Aug 28, 2015·Chemical Reviews·Andreas NordheiderTristram Chivers
May 11, 2013·The Journal of Physical Chemistry. B·Seiji Tsuzuki, Naoki Sato
Jan 15, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Lucia M LeeIgnacio Vargas-Baca
Oct 30, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Saurabh S Chitnis, Neil Burford
Aug 8, 2018·Chemistry : a European Journal·Nikolay A PushkarevskyAndrey V Zibarev
Sep 18, 2010·Chemistry : a European Journal·Jason L Dutton, Paul J Ragogna
Dec 22, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Andreas NordheiderIgnacio Vargas-Baca
Aug 1, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Lucia Myongwon LeeIgnacio Vargas-Baca
May 3, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Eric Rivard
Aug 28, 2009·Chemistry : a European Journal·Jason L DuttonPaul J Ragogna
Dec 20, 2011·Chemical Communications : Chem Comm·S M Ibrahim Al-RafiaEric Rivard
Feb 3, 2021·Angewandte Chemie·Xiangjin KongYao Wang
Apr 13, 2010·Inorganic Chemistry·Caleb D Martin, Paul J Ragogna
May 28, 2019·Journal of the American Chemical Society·Wei WangYao Wang
Jul 4, 2018·Chemical Reviews·Vitaly NesterovShigeyoshi Inoue
Jan 22, 2020·Journal of the American Chemical Society·Wei WangYao Wang

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