Doubly phenoxo-hydroxo-bridged dicopper(II) complexes: individual contributions of the bridges to antiferromagnetic coupling based on two related biomimetic models for catechol oxidases

Dalton Transactions : an International Journal of Inorganic Chemistry
Nicolás A ReyZbigniew Tomkowicz

Abstract

This paper describes the synthesis, structure and spectroscopic and magnetic properties of two (μ-phenoxo)(μ-hydroxo)dicopper(II) complexes (1 and 2) which contain similar N,O-donor atoms but with distinct coordination arrangements around the Cu(II) centers. Structural and magnetic studies of 1 and 2 allowed us to evaluate, for the first time, the individual contributions of the {Cu(μ-phenoxo)Cu} and {Cu(μ-hydroxo)Cu} structural units to the antiferromagnetic coupling between the Cu(II) centers in these complexes.

References

Dec 10, 1998·Nature Structural Biology·T KlabundeB Krebs
Mar 20, 2002·Accounts of Chemical Research·Carsten GerdemannBernt Krebs
Sep 28, 2004·Journal of Biological Inorganic Chemistry : JBIC : a Publication of the Society of Biological Inorganic Chemistry·Alessandro GranataLuigi Casella
Nov 24, 2004·Inorganic Chemistry·Silvio AimeMassimo Sisti
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Jan 12, 2008·Journal of Biological Inorganic Chemistry : JBIC : a Publication of the Society of Biological Inorganic Chemistry·Sarah J SmithMark J Riley

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Citations

Mar 17, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Krishna ChattopadhyayDebashis Ray
May 9, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Kelly A D F CastroMário M Q Simões
Jan 25, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Aloke Kumar GhoshDebashis Ray
Dec 5, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Tomáš DavidIvan Lukeš
Jul 6, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·J A IsaacC Belle
Aug 22, 2021·Journal of Biological Inorganic Chemistry : JBIC : a Publication of the Society of Biological Inorganic Chemistry·Jesica Paola RadaVincent Corcé

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