Effect of eggshell- and homo-type Ni/Al2O3 catalysts on the pyrolysis of food waste under CO2 atmosphere.

Journal of Environmental Management
Soheil ValizadehYoung-Kwon Park

Abstract

This study highlights the potential of pyrolysis of food waste (FW) with Ni-based catalysts under CO2 atmosphere as an environmentally benign disposal technique. FW was pyrolyzed with homo-type Ni/Al2O3 (Ni-HO) or eggshell-type Ni/Al2O3 (Ni-EG) catalysts under flowing CO2 (50 mL/min) at temperatures from 500 to 700 °C for 1 h. A higher gas yield (42.05 wt%) and a lower condensable yield (36.28 wt%) were achieved for catalytic pyrolysis with Ni-EG than with Ni-HO (34.94 wt% and 40.06 wt%, respectively). In particular, the maximum volumetric content of H2 (21.48%) and CO (28.43%) and the lowest content of C2-C4 (19.22%) were obtained using the Ni-EG. The formation of cyclic species (e.g., benzene derivatives) in bio-oil was also effectively suppressed (24.87%) when the Ni-EG catalyst and CO2 medium were concurrently utilized for the FW pyrolysis. Accordingly, the simultaneous use of the Ni-EG catalyst and CO2 contributed to altering the carbon distribution of the pyrolytic products from condensable species to value-added gaseous products by facilitating ring-opening reactions and free radical mechanisms. This study should suggest that CO2-assisted catalytic pyrolysis over the Ni-EG catalyst would be an eco-friendly and sustainabl...Continue Reading

References

Jan 15, 2011·Bioresource Technology·Huiyan ZhangZhaoping Zhong
Aug 26, 2014·Applied Biochemistry and Biotechnology·Zheng SunCarol Sze Ki Lin
Jul 10, 2019·The Science of the Total Environment·Najam Ul SaqibAjit K Sarmah
Oct 23, 2019·Environment International·Dong-Jun LeeEilhann E Kwon
Mar 11, 2020·Journal of Hazardous Materials·Soosan Kim, Jechan Lee
Apr 17, 2020·Journal of Hazardous Materials·Peter Nai Yuh YekSu Shiung Lam
Dec 2, 2020·Environmental Pollution·Jianqiao WangChunfei Wu
Feb 14, 2021·Environmental Pollution·Seong Heon ChoEilhann E Kwon

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